Caramelization

Classic brown caramelized crust on a Crème brûlée

Caramelization or caramelisation is the browning of sugar, a process used extensively in cooking for the resulting sweet nutty flavor and brown color. The brown colors are produced by three groups of polymers: caramelans (C₂₄H₃₆O₁₈), caramelens (C₃₆H₅₀O₂₅), and caramelins (C₁₂₅H₁₈₈O₈₀). As the process occurs, volatile chemicals such as diacetyl are released, producing the characteristic caramel flavor.^[1]

Like the Maillard reaction, caramelization is a type of non-enzymatic browning. Unlike the Maillard reaction, caramelization is pyrolytic, as opposed to being a reaction with amino acids.

When caramelization involves the disaccharide sucrose, it is broken down into the monosaccharides fructose and glucose.^[2]

Process

Caramelization is a complex, poorly understood process that produces hundreds of chemical products, and includes the following types of reactions:

equilibration of anomeric and ring forms
sucrose inversion to fructose and glucose
condensation reactions
intramolecular bonding
isomerization of aldoses to ketoses
dehydration reactions
fragmentation reactions
unsaturated polymer formation

Effects on caramelization

The process is temperature-dependent. Specific sugars each have their own point at which the reactions begin to proceed readily. Impurities in the sugar, such as the molasses remaining in brown sugar, greatly speed the reactions.

Caramelization temperatures^[3]
Sugar	Temperature
Fructose	105 °C (221 °F)
Galactose	160 °C (320 °F)
Glucose	150 °C (302 °F)
Sucrose	170 °C (338 °F)
Maltose	180 °C (360 °F)

Caramelization reactions are also sensitive to the chemical environment,^[4] and the reaction rate, or temperature at which reactions occur most readily, can be altered by controlling the level of acidity (pH). The rate of caramelization is generally lowest at near-neutral acidity (pH around 7), and accelerated under both acidic (especially pH below 3) and basic (especially pH above 9) conditions.^[5]

Uses in food

Caramelization is used to produce several foods, including:

Caramel sauce, a sauce made with caramel
Confiture de lait and Dulce de leche, caramelized, sweetened milk
Caramel candies
Creme Caramel, and the similar crème brûlée, a custard dish topped with sugar caramelized with a blowtorch
Caramelized onions, which are used in dishes like French onion soup. Onions require 30 to 45 minutes of cooking to caramelize.^[6]^[7]
Caramelized potatoes
Caramelized pears^[8]
Cola, of which some brands use caramelized sugar in small amounts for color

Caramelization reactions involves Maillard reaction, a browning reaction due to interactions between protein or high amino acid ingredients with reducing sugars. Besides appearance change, caramelization may also influence the taste and texture of the food due to the Maillard reaction.^[9]

References

^ Miller, Dennis (1998). Food Chemistry: A Laboratory Manual. Wiley-Interscience. ISBN 978-0471175438.
^ Woo, K. S.; Kim, H. Y.; Hwang, I. G.; Lee, S. H.; Jeong, H. S. (2015). "Characteristics of the Thermal Degradation of Glucose and Maltose Solutions". Prev Nutr Food Sci. 20 (2): 102–9. doi:10.3746/pnf.2015.20.2.102. PMC 4500512. PMID 26175997.
^ Harold McGee. "On Food and Cooking", 2nd Edition (2004), Scribner, New York, NY. "Sugar, Chocolate and Confectionery", Page 656.
^ McGee, Harold. "Caramelization: new science, new possibilities". Retrieved 10 May 2019. {{cite news}}: |archive-date= requires |archive-url= (help)
^ Villamiel, M.; del Castillo, M. D.; Corzo, N. (2006). "4. Browning Reactions". In Hui, Y. H.; Nip, W-.K.; Nollet. L. M. L.; Paliyath, G.; Simpson, B. K. (eds.). Food biochemistry and food processing. Wiley-Blackwell. pp. 83–85. ISBN 978-0-8138-0378-4.
^ Scocca, Tom. Layers of Deceit: Why do recipe writers lie and lie and lie about how long it takes to caramelize onions? Slate.com, May 2, 2012.
^ Child, Julia. "French Onion Soup". Archived from the original on 2012-05-02. Retrieved 2017-03-08.
^ Farley, Jennifer (2016-10-10). "Caramelizing Pears". Stemilt. Retrieved 2016-10-27.
^ Starowicz, Małgorzata; Zieliński, Henryk (2019-11-17). "How Maillard Reaction Influences Sensorial Properties (Color, Flavor and Texture) of Food Products?". Food Reviews International. 35 (8): 707–725. doi:10.1080/87559129.2019.1600538. ISSN 8755-9129.

squid games

External links

Caramelization at Science of Cooking

[1] Miller, Dennis (1998). Food Chemistry: A Laboratory Manual. Wiley-Interscience. ISBN 978-0471175438.

[2] Woo, K. S.; Kim, H. Y.; Hwang, I. G.; Lee, S. H.; Jeong, H. S. (2015). "Characteristics of the Thermal Degradation of Glucose and Maltose Solutions". Prev Nutr Food Sci. 20 (2): 102–9. doi:10.3746/pnf.2015.20.2.102. PMC 4500512. PMID 26175997.

[3] Harold McGee. "On Food and Cooking", 2nd Edition (2004), Scribner, New York, NY. "Sugar, Chocolate and Confectionery", Page 656.

[4] McGee, Harold. "Caramelization: new science, new possibilities". Retrieved 10 May 2019. {{cite news}}: |archive-date= requires |archive-url= (help)

[5] Villamiel, M.; del Castillo, M. D.; Corzo, N. (2006). "4. Browning Reactions". In Hui, Y. H.; Nip, W-.K.; Nollet. L. M. L.; Paliyath, G.; Simpson, B. K. (eds.). Food biochemistry and food processing. Wiley-Blackwell. pp. 83–85. ISBN 978-0-8138-0378-4.

[6] Scocca, Tom. Layers of Deceit: Why do recipe writers lie and lie and lie about how long it takes to caramelize onions? Slate.com, May 2, 2012.

[7] Child, Julia. "French Onion Soup". Archived from the original on 2012-05-02. Retrieved 2017-03-08.

[8] Farley, Jennifer (2016-10-10). "Caramelizing Pears". Stemilt. Retrieved 2016-10-27.

[9] Starowicz, Małgorzata; Zieliński, Henryk (2019-11-17). "How Maillard Reaction Influences Sensorial Properties (Color, Flavor and Texture) of Food Products?". Food Reviews International. 35 (8): 707–725. doi:10.1080/87559129.2019.1600538. ISSN 8755-9129.

[1]

[2]

[3]

[4]

[5]

[6]

[7]

[8]

[9]

Process

Effects on caramelization

Uses in food

See also

References

External links