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Isotopes of beryllium

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Isotopes of beryllium (4Be)
Main isotopes[1] Decay
abun­dance half-life (t1/2) mode pro­duct
7Be trace 53.22 d ε 7Li
8Be synth 81.9 as α 4He
9Be 100% stable
10Be trace 1.387×106 y β− 10B
Standard atomic weight Ar°(Be)

Beryllium (4Be) has 11 known isotopes and 3 known isomers, but only one of these isotopes (9
Be
) is stable and a primordial nuclide. As such, beryllium is considered a monoisotopic element. It is also a mononuclidic element, because its other isotopes have such short half-lives that none are primordial and their abundance is very low (standard atomic weight is 9.0121831(5)). Beryllium is unique as being the only monoisotopic element with both an even number of protons and an odd number of neutrons. There are 25 other monoisotopic elements but all have odd atomic numbers, and even numbers of neutrons.

Of the 10 radioisotopes of beryllium, the most stable are 10
Be
 with a half-life of 1.387(12) million years[nb 1] and 7
Be
 with a half-life of 53.22(6) d. All other radioisotopes have half-lives under 15 s, most under 30 milliseconds. The least stable isotope is 16
Be
, with a half-life of 650(130) yoctoseconds.

The 1:1 neutron–proton ratio seen in stable isotopes of many light elements (up to oxygen, and in elements with even atomic number up to calcium) is prevented in beryllium by the extreme instability of 8
Be
 toward alpha decay, which is favored due to the extremely tight binding of 4
He
 nuclei. The half-life for the decay of 8
Be
 is only 81.9(3.7) attoseconds.

Beryllium is prevented from having a stable isotope with 4 protons and 6 neutrons by the very large mismatch in neutron–proton ratio for such a light element. Nevertheless, this isotope, 10
Be
, has a half-life of 1.387(12) million years[nb 1], which indicates unusual stability for a light isotope with such a large neutron/proton imbalance. Other possible beryllium isotopes have even more severe mismatches in neutron and proton number, and thus are even less stable.

Most 9
Be
 in the universe is thought to be formed by cosmic ray nucleosynthesis from cosmic ray spallation in the period between the Big Bang and the formation of the solar system. The isotopes 7
Be
, with a half-life of 53.22(6) d, and 10
Be
 are both cosmogenic nuclides because they are made on a recent timescale in the solar system by spallation,[4] like 14
C
. These two radioisotopes of beryllium in the atmosphere track the sunspot cycle and solar activity, since this affects the magnetic field that shields the Earth from cosmic rays. The rate at which the short-lived 7
Be
 is transferred from the air to the ground is controlled in part by the weather. 7
Be
 decay in the sun is one of the sources of solar neutrinos, and the first type ever detected using the Homestake experiment. Presence of 7
Be
 in sediments is often used to establish that they are fresh, i.e. less than about 3–4 months in age, or about two half-lives of 7
Be
.

The rate of delivery of 7
Be
 from the air to the ground in Japan (source M. Yamamoto et al., Journal of Environmental Radioactivity, 2006, 8, 110–131)

List of isotopes

Nuclide
[n 1] 		Z N Isotopic mass (Da)[5]
[n 2][n 3] 		Half-life[1]

[resonance width] 		Decay
mode[1]
[n 4] 		Daughter
isotope
[n 5] 		Spin and
parity[1]
[n 6] 		Isotopic
abundance
Excitation energy
5
Be
 		4 1 5.03987(215)# p ?[n 7] 4
Li
 		(1/2+)#
6
Be
 		4 2 6.019726(6) 5.0(3) zs
[91.6(5.6) keV] 		2p 4
He
 		0+
7
Be
[n 8] 		4 3 7.01692871(8) 53.22(6) d EC 7
Li
 		3/2− Trace[n 9]
8
Be
[n 10] 		4 4 8.00530510(4) 81.9(3.7) as
[5.58(25) eV] 		α 4
He
 		0+
8m
Be
 		16626(3) keV α 4
He
 		2+
9
Be
 		4 5 9.01218306(8) Stable 3/2− 1
9m
Be
 		14390.3(1.7) keV 1.25(10) as
[367(30) eV] 		3/2−
10
Be
 		4 6 10.01353469(9) 1.387(12)×106 y[nb 1] β− 10
B
 		0+ Trace[n 9]
11
Be
[n 11] 		4 7 11.02166108(26) 13.76(7) s β− (96.7(1)%) 11
B
 		1/2+
β−α (3.3(1)%) 7
Li
β−p (0.0013(3)%) 10
Be
11m
Be
 		21158(20) keV 0.93(13) zs
[500(75) keV] 		IT ?[n 7] 11
Be
 		3/2−
12
Be
 		4 8 12.0269221(20) 21.46(5) ms β− (99.50(3)%) 12
B
 		0+
β−n (0.50(3)%) 11
B
12m
Be
 		2251(1) keV 233(7) ns IT 12
Be
 		0+
13
Be
 		4 9 13.036135(11) 1.0(7) zs n ?[n 7] 12
Be
 		(1/2−)
13m
Be
 		1500(50) keV (5/2+)
14
Be
[n 12] 		4 10 14.04289(14) 4.53(27) ms β−n (86(6)%) 13
B
 		0+
β− (> 9.0(6.3)%) 14
B
β−2n (5(2)%) 12
B
β−, fission (0.02(1)%) 11
Be
, 3
H
β−α (< 0.004%) 10
Li
14m
Be
 		1520(150) keV (2+)
15
Be
 		4 11 15.05349(18) 790(270) ys n 14
Be
 		(5/2+)
16
Be
 		4 12 16.06167(18) 650(130) ys
[0.73(18) MeV] 		2n 14
Be
 		0+
This table header & footer:
  1. ^ mBe – Excited nuclear isomer.
  2. ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  5. ^ Bold symbol as daughter – Daughter product is stable.
  6. ^ ( ) spin value – Indicates spin with weak assignment arguments.
  7. ^ a b c Decay mode shown is energetically allowed, but has not been experimentally observed to occur in this nuclide.
  8. ^ Produced in Big Bang nucleosynthesis, but not primordial, as it all quickly decayed to 7Li
  9. ^ a b cosmogenic nuclide
  10. ^ Intermediate product of triple alpha process in stellar nucleosynthesis as part of the path producing 12C
  11. ^ Has 1 halo neutron
  12. ^ Has 4 halo neutrons

Decay chains

Most isotopes of beryllium within the proton/neutron drip lines decay via beta decay and/or a combination of beta decay and alpha decay or neutron emission. However, 7Be decays only via electron capture, a phenomenon to which its unusually long half-life may be attributed. Notably, its half-life can be artificially lowered by 0.83% via endohedral enclosure (7Be@C60).[6] Also anomalous is 8Be, which decays via alpha decay to 4He. This alpha decay is often considered fission, which would be able to account for its extremely short half-life.

Notes

  1. ^ a b c Note that NUBASE2020 uses the tropical year to convert between years and other units of time, not the Gregorian year. The relationship between years and other time units in NUBASE2020 is as follows: 1 y = 365.2422 d = 31 556 926 s

References

  1. ^ a b c d Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. ^ "Standard Atomic Weights: Beryllium". CIAAW. 2013.
  3. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. ^ Mishra, Ritesh Kumar; Marhas, Kuljeet Kaur (2019-03-25). "Meteoritic evidence of a late superflare as source of 7 Be in the early Solar System". Nature Astronomy. 3 (6): 498–505. doi:10.1038/s41550-019-0716-0. ISSN 2397-3366.
  5. ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  6. ^ Ohtsuki, T.; Yuki, H.; Muto, M.; Kasagi, J.; Ohno, K. (9 September 2004). "Enhanced Electron-Capture Decay Rate of 7Be Encapsulated in C60 Cages". Physical Review Letters. 93 (11): 112501. doi:10.1103/PhysRevLett.93.112501. Retrieved 23 February 2022.
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